The first law of thermodynamics is a statement of the law of conservation of energy applied to thermodynamic systems. When a small amount of heat d Q dQ is supplied to a thermodynamic system, a part of it may be used to increase the internal energy of the system, while the remaining part may be used to do external work . Thus, d Q = d U + d W \boxed{dQ=dU+dW} where d Q dQ = infinitesimal amount of heat supplied to the system, d U dU = infinitesimal change in internal energy, d W dW = infinitesimal work done by the system. If the system performs work d W dW against an external pressure P e x t P_{\rm ext} , d W = P e x t d V \boxed{dW=P_{\rm ext}\,dV} Therefore, d Q = d U + P e x t d V \boxed{dQ=dU+P_{\rm ext}\,dV} For a quasi-static process , P e x t = P P_{\rm ext}=P , so d Q = d U + P d V \boxed{dQ=dU+P\,dV}
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