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ऐसा बनना कि लोगों की तुम सहायता कर सको, लोग तुम्हारी नहीं ।।

Determination of Elastic Constants by Searle's Method

Elastic Constants by Searle's Dynamical Method 1. Aim To determine Young's modulus \(Y\), modulus of rigidity \(n\), and Poisson's ratio \(\sigma\) of the material of a given wire by Searle's dynamical method using the time periods of oscillation. 2. Apparatus Required Searle's dynamical apparatus, two identical cylindrical bars, experimental wire, rigid supporting stand, stopwatch, screw gauge, vernier calipers, metre scale and physical balance. 3. Theory When an elastic body is deformed within its elastic limit, restoring forces or couples are developed. These restoring actions tend to bring the body back to its original configuration. Searle's dynamical method determines the elastic constants of a wire by observing two independent modes of oscillation of an arrangement containing the wire and two identical bars. The first mode is associated with flexural deformation, while the second mode involves torsional deformation. Th...

Experiment: Bending of a Beam

Experiment: Non-Uniform Bending of a Beam Study of Bending of a Beam and Determination of Young's Modulus Method: Non-Uniform Bending (Central Loading Method) 1. Aim To study the non-uniform bending of a rectangular beam supported on two knife edges and to determine Young's modulus of the material by applying a load at the centre of the beam. 2. Apparatus Required Rectangular beam (metallic or wooden), two knife-edge supports, weight hanger, slotted weights, travelling microscope, metre scale, Vernier calipers and screw gauge. 3. Theory When a rectangular beam is supported horizontally on two knife edges and a load is applied at its midpoint, the beam bends downward. The bending moment varies along the length of the beam; therefore, this type of bending is called non-uniform bending . For a simply supported beam carrying a central load, the depression at the midpoint is given by \[ y=\frac{Wl^3}{48YI} ...

Properties of Matter: Elasticity, stress and strain

Elasticity 1. Elasticity When an external force acts on a solid body, its dimensions or shape may change. This change is called deformation . Depending on the direction and nature of the applied force, deformation may involve a change in length, volume, shape, or a combination of these. For example: A wire undergoes elongation when a tensile force acts along its length. A solid body undergoes a change in volume when subjected to uniform external pressure. A block undergoes a change in shape when a tangential force acts on its surface. In crystalline solids, deformation generally involves changes in interatomic distances and bond angles. In rubber and other polymers, deformation may also involve the uncoiling, orientation, and stretching of polymer chains. Elasticity: Elasticity is the property of a material by virtue of which it tends to regain its original shape and dimensions after the removal of the external deforming force, provided that th...

Equilibrium Conditions for a System at Constant Pressure in Contact with a Heat Reservoir: Enthalpy

Consider a closed thermodynamic system \(A\) consisting of a gas enclosed in a cylinder fitted with a frictionless movable piston. The system is in thermal contact with a large heat reservoir maintained at temperature \(T_0\). The external pressure \(P_0\) remains constant. When the system absorbs heat from the reservoir, the gas may expand and perform pressure–volume work against the surroundings. Suppose the system absorbs heat \(Q\) and undergoes a change in volume \(\Delta V\). The work done by the gas against the constant external pressure is \[ \Delta W=P_0\Delta V. \] From the first law of thermodynamics, \[ \Delta U=Q-\Delta W. \] Therefore, \[ Q=\Delta U+P_0\Delta V. \] Since \(P_0\) is constant, \[ Q=\Delta(U+P_0V). \] A thermodynamic state function called enthalpy is defined as \[ \boxed{H=U+PV} \tag{1} \] For initial and final equilibrium states at the same constant pressure \(P=P_0\), and when only pressure–volu...

Equilibrium Conditions for a System of Fixed Volume in Contact with a Heat Reservoir: Helmholtz Free Energy

Consider a closed thermodynamic system \(A\) in thermal contact with a large heat reservoir \(A'\) maintained at a constant temperature \(T_0\). The system is enclosed within rigid walls, so its volume remains constant. Only heat is exchanged between the system and the reservoir, and no external work is performed. Let the system absorb an amount of heat \(Q\) from the reservoir. Since the reservoir loses the same amount of heat, its entropy change is \[ \boxed{ \Delta S'=-\frac{Q}{T_0} } \tag{1} \] From the first law of thermodynamics, \[ \Delta U=Q-W. \] At constant volume, assuming only pressure–volume work, \[ W=\int P_{\mathrm{ext}}\,dV=0. \] Therefore, \[ \boxed{Q=\Delta U} \tag{2} \] Substituting equation (2) into equation (1), \[ \boxed{ \Delta S'=-\frac{\Delta U}{T_0} } \tag{3} \] The combined system consisting of \(A\) and the heat reservoir \(A'\) is thermally isolated from the surroundings. Henc...

Vapour in Equilibrium with a Liquid or Solid

When the vapour of a substance is in thermodynamic equilibrium with its liquid or solid phase at a given temperature, the pressure exerted by the vapour is called the saturated vapour pressure . The dependence of saturated vapour pressure on temperature is described by the Clapeyron equation. For two phases in equilibrium, the Clapeyron equation is \[ \boxed{ \frac{dP}{dT} = \frac{L}{T(V_2-V_1)} } \tag{1} \] where \(L\) is the molar latent heat of transition. \(V_1\) is the molar volume of the condensed phase. \(V_2\) is the molar volume of the vapour phase. \(T\) is the absolute temperature. For vaporization or sublimation at sufficiently low pressure, the molar volume of the vapour is much larger than that of the liquid or solid: \[ V_2\gg V_1. \] Therefore, \[ V_2-V_1\approx V_2. \] Equation (1) becomes \[ \frac{dP}{dT} \approx \frac{L}{TV_2}. \tag{2} \] Assuming that the vapour behaves as an ideal gas, the equation of sta...

Triple point

Thermodynamic Equilibrium and Phase Transitions Triple Point A pure substance may exist in three principal phases: solid, liquid, and vapour. The equilibrium state of a substance is determined by its thermodynamic variables, particularly pressure \(P\) and temperature \(T\). A change in pressure or temperature may cause a phase transition. The equilibrium between different phases can be represented by a pressure–temperature (\(P\)–\(T\)) phase diagram. Consider the phase diagram of water, which contains three phase-equilibrium curves: Solid–liquid equilibrium curve (fusion curve). Liquid–vapour equilibrium curve (vaporization curve). Solid–vapour equilibrium curve (sublimation curve). Pressure–Temperature Phase Diagram of Water Temperature (T) Pressure (P) Critical point Solid Liquid Vapour Fusion curve Vaporization curve Sublimation curve Triple point Tₜ Pₜ Fig. 3.10.1: Schematic pressu...

Equilibrium Between Phases

A change in temperature or pressure may cause a substance to transform from one phase into another. This transformation is called a phase transition . The principal phase transitions are: Melting: Transformation from solid to liquid. Freezing: Transformation from liquid to solid. Vaporization: Transformation from liquid to vapour. Condensation: Transformation from vapour to liquid. Sublimation: Direct transformation from solid to vapour. Deposition: Direct transformation from vapour to solid. During phase equilibrium, two phases coexist without any net transfer of matter from one phase to the other, although molecular exchange may continue in both directions. Thermodynamic Condition for Phase Equilibrium Consider a closed system containing two phases, denoted by phase 1 and phase 2, of the same pure substance. The phases are in thermal and mechanical contact and are allowed to exchange molecules. The system is maintained at ...